You can also upgrade iCloud storage on Mac, iPhone/iPad. Click here for details.

Mac - iCloud Storage Upgrade (Purchase) iPhone/iPad - iCloud Storage Upgrade (Purchase)

To use iCloud on Windows, you need to install “iCloud Control Panel”. First, let’s start the installation by referring to here.

How to use iCloud on Windows

Windows - Upgrade (Purchase) iCloud Storage

Windows8 - show/hide system icons in notification area

In this way the capacity is increased to 20 GB.